Course Chemical Bonds: Covalent Bonding and Shapes of Molecules (20)

sp Hybrid Orbitalsโ€”Bond Angles of Approximately 180ยฐ

In sp hybridization, only one p orbital participates in the hybridization with the s orbital.

If we looked at sp hybridization of carbon atom, carbon’s 2s orbital hybridizes with one of the 2p orbitals, resulting in the formation of two sp hybridized orbitals, while the other two 2p orbitals remain unhybridized.

carbon sp hybridization

The hybridization of one s and one p orbital yields two sp orbitals with 50% s character and 50% p character.

s:p character in sp hybridization

The angle between the two hybridized orbitals is 180 degrees, indicating that both sp orbitals lie on the same plane, while the two unhybridized 2p orbitals are perpendicular to the sp hybridized orbitals.

sp in plane and 2p propondicular to the plane orbitals in sp carbon hybridization

Notice that, the unhybridized 2p orbitals are the ones form pi bonds, that is why we expect two pi bonds.

Acetylene molecule

Let’s examine the acetylene molecule. Each carbon atom in acetylene possesses two sp hybridized orbitals and two unhybridized 2p orbitals, totaling four sp orbitals and four 2p orbitals for the two carbon atoms.

Acetylene molecular structure

Acetylene also contains two hydrogen atoms with two 1s orbitals.

The molecule’s bonds consist of:

Two sigma C-H bonds formed by overlapping the two sp orbitals of each carbon with the hydrogen 1s orbitals.

One sigma C-C bond formed by overlapping the two sp carbon orbitals of each carbon.

Two C-C pi bonds formed by overlapping the four 2p orbitals.

Acetylene  3d molecular orbital structure

In total, acetylene comprises five bonds: two sigma carbon-hydrogen bonds, one sigma carbon-carbon bond, and two carbon-carbon pi bonds.

Read about:

sp3 Hybridization: Covalent Bonds (18)
sp2 Hybridization: Covalent Bonds Course (19)

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Covalent Bonding and Shape of Molecules

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Category: Chemical Bonds: Covalent Bonding and Shape of Molecules